NCT05501366

Brief Summary

One important difference between KE compounds is the ketone-promoting components, which determines the circulating ratio of blood ketone bodies, BHB and AcAc, and may in turn lead to important metabolic and signaling differences. Whereas some actions of the ketone bodies BHB and AcAc are shared, R-BHB has a broad range of signaling functions that are distinct from AcAc, some of which are shared by the non-circulating, non-oxidizable enantiomer, S-BHB. AcAc also has metabolic and signaling actions that are independent of BHB and is selectively oxidized in some cells that cannot oxidize BHB. Furthermore, responses to different ketone bodies vary between tissue types. A second difference between KE arises from the balance between direct delivery of ketones compared to indirectly elevating ketone concentration via metabolism of non-classical or classical ketogenic precursors. Classical ketogenesis itself may drive adaptation and some of the functional benefits associated with ketosis. BDO is included in all of the KE compounds, but it is currently unknown how consumption of BDO alone, and its metabolism via non-classical ketogenesis acutely affects metabolism. Additionally, ketogenesis is now understood to occur in certain cells outside the liver with important local biological effects, for example ketogenesis driven by medium chain fatty acids has been reported in astrocytes in vitro. Provision of systemic BHB by a KE may elicit different biological effects in some tissues such as the brain versus promoting in situ ketogenesis in that tissue. Overall, not only are functional effects of KE incompletely defined, but also it is unknown which effects are common to all KE versus which are specific to an individual KE compound (i.e., BHB Monoester vs AcAc Diester) or which may be attributable to the BDO precursor common to all of the KE. This study will be the first comparative full crossover study of all available KE and the precursor BDO at two serving sizes. Outcomes will focus on established effects of the BHB Monoester (including the effects on ketones, glucose and acid-base balance) and compare these with the effects of the AcAc Diester, C8 Ketonef Diester and BDO.

Trial Health

75
On Track

Trial Health Score

Automated assessment based on enrollment pace, timeline, and geographic reach

Enrollment
14

participants targeted

Target at below P25 for not_applicable

Timeline
16mo left

Started Jun 2023

Longer than P75 for not_applicable

Geographic Reach
1 country

1 active site

Status
active not recruiting

Health score is calculated from publicly available data and should be used for screening purposes only.

Trial Relationships

Click on a node to explore related trials.

Study Timeline

Key milestones and dates

Study Progress69%
Jun 2023Sep 2027

First Submitted

Initial submission to the registry

August 1, 2022

Completed
14 days until next milestone

First Posted

Study publicly available on registry

August 15, 2022

Completed
10 months until next milestone

Study Start

First participant enrolled

June 5, 2023

Completed
3.2 years until next milestone

Primary Completion

Last participant's last visit for primary outcome

September 1, 2026

Expected
1 year until next milestone

Study Completion

Last participant's last visit for all outcomes

September 1, 2027

Last Updated

May 29, 2025

Status Verified

May 1, 2025

Enrollment Period

3.2 years

First QC Date

August 1, 2022

Last Update Submit

May 28, 2025

Conditions

Outcome Measures

Primary Outcomes (1)

  • Total Plasma Ketone AUC

    Difference in total plasma ketone appearance (AUC) between the two serving sizes of study products and control

    Up to ~ 4 weeks

Secondary Outcomes (16)

  • Capillary d-BHB concentrations

    Up to ~ 4 weeks

  • AcAc, R-BHB and S-BHB changes across trials

    Up to ~ 4 weeks

  • Continuous Ketone and Glucose Monitoring

    Up to ~ 4 weeks

  • Ketone Excretion

    Up to ~ 4 weeks

  • Ketone in breathe expiration

    Up to ~ 4 weeks

  • +11 more secondary outcomes

Study Arms (9)

BHB Mono-ester 180mg/kg

EXPERIMENTAL
Dietary Supplement: Ketone SupplementBehavioral: Beverage Tolerability Questionnaire (BTQ) and satiety visual analogue scaleBiological: Blood DrawOther: Breath ReadingOther: Heart Rate VariabilityOther: CGM/CKMOther: Urine Analysis

BHB mono-ester 360mg/kg

EXPERIMENTAL
Dietary Supplement: Ketone SupplementBehavioral: Beverage Tolerability Questionnaire (BTQ) and satiety visual analogue scaleBiological: Blood DrawOther: Breath ReadingOther: Heart Rate VariabilityOther: CGM/CKMOther: Urine Analysis

C8 Ketone Di-ester 180mg/kg

EXPERIMENTAL
Dietary Supplement: Ketone SupplementBehavioral: Beverage Tolerability Questionnaire (BTQ) and satiety visual analogue scaleBiological: Blood DrawOther: Breath ReadingOther: Heart Rate VariabilityOther: CGM/CKMOther: Urine Analysis

C8 Ketone Di-ester 360mg/kg

EXPERIMENTAL
Dietary Supplement: Ketone SupplementBehavioral: Beverage Tolerability Questionnaire (BTQ) and satiety visual analogue scaleBiological: Blood DrawOther: Breath ReadingOther: Heart Rate VariabilityOther: CGM/CKMOther: Urine Analysis

AcAc Di-ester 180mg/kg

EXPERIMENTAL
Dietary Supplement: Ketone SupplementBehavioral: Beverage Tolerability Questionnaire (BTQ) and satiety visual analogue scaleBiological: Blood DrawOther: Breath ReadingOther: Heart Rate VariabilityOther: CGM/CKMOther: Urine Analysis

AcAc Di-ester 360mg/kg

EXPERIMENTAL
Dietary Supplement: Ketone SupplementBehavioral: Beverage Tolerability Questionnaire (BTQ) and satiety visual analogue scaleBiological: Blood DrawOther: Breath ReadingOther: Heart Rate VariabilityOther: CGM/CKMOther: Urine Analysis

(R)-1,3 butanediol 180mg/kg

EXPERIMENTAL
Dietary Supplement: Ketone SupplementBehavioral: Beverage Tolerability Questionnaire (BTQ) and satiety visual analogue scaleBiological: Blood DrawOther: Breath ReadingOther: Heart Rate VariabilityOther: CGM/CKMOther: Urine Analysis

(R)-1,3 butanediol 360mg/kg

EXPERIMENTAL
Dietary Supplement: Ketone SupplementBehavioral: Beverage Tolerability Questionnaire (BTQ) and satiety visual analogue scaleBiological: Blood DrawOther: Breath ReadingOther: Heart Rate VariabilityOther: CGM/CKMOther: Urine Analysis

Control

PLACEBO COMPARATOR
Dietary Supplement: Ketone SupplementBehavioral: Beverage Tolerability Questionnaire (BTQ) and satiety visual analogue scaleBiological: Blood DrawOther: Breath ReadingOther: Heart Rate VariabilityOther: CGM/CKMRadiation: DXAOther: Urine Analysis

Interventions

Ketone SupplementDIETARY_SUPPLEMENT

Four different exogenous ketone products at two serving sizes or a non-ketogenic placebo (one study product per test day). 1) Monoester of BHB (R)-1,3 butanediol (BHB Mono-ester), 2) diester of hexanoic acid (a ketogenic medium chain fatty acid) and (R)-1,3 butanediol (C6 Di-ester) 3) diester of AcAc and (R,S)-1,3 butanediol (AcAc Di-ester) \& 4) (R) -1,3 butanediol only (BDO). All products will be delivered in 2 different dosages 180mg/kg and 360mg/kg on separate testing days.

(R)-1,3 butanediol 180mg/kg(R)-1,3 butanediol 360mg/kgAcAc Di-ester 180mg/kgAcAc Di-ester 360mg/kgBHB Mono-ester 180mg/kgBHB mono-ester 360mg/kgC8 Ketone Di-ester 180mg/kgC8 Ketone Di-ester 360mg/kgControl

Beverage Tolerability Questionnaire (BTQ) and satiety visual analogue scale will be administered at beginning and end of testing day to tests palatability of supplement

(R)-1,3 butanediol 180mg/kg(R)-1,3 butanediol 360mg/kgAcAc Di-ester 180mg/kgAcAc Di-ester 360mg/kgBHB Mono-ester 180mg/kgBHB mono-ester 360mg/kgC8 Ketone Di-ester 180mg/kgC8 Ketone Di-ester 360mg/kgControl
Blood DrawBIOLOGICAL

IV cannula will be inserted at the start of each Test Day, and removed at the end of each Test Day, Blood samples will be collected according to the schedule in Figure 1. Cannula will be flushed with a small volume of saline after each sample to maintain patency. We will draw 504 mL of blood, which is about 2.1 cups throughout the 4-week intervention

(R)-1,3 butanediol 180mg/kg(R)-1,3 butanediol 360mg/kgAcAc Di-ester 180mg/kgAcAc Di-ester 360mg/kgBHB Mono-ester 180mg/kgBHB mono-ester 360mg/kgC8 Ketone Di-ester 180mg/kgC8 Ketone Di-ester 360mg/kgControl

Participants will breathe into a commercially available handheld breath acetone analyzer according to the schedule. Participants will wear a fitted face mask attached to a metabolic cart for a 10-minute period every 60 minutes

(R)-1,3 butanediol 180mg/kg(R)-1,3 butanediol 360mg/kgAcAc Di-ester 180mg/kgAcAc Di-ester 360mg/kgBHB Mono-ester 180mg/kgBHB mono-ester 360mg/kgC8 Ketone Di-ester 180mg/kgC8 Ketone Di-ester 360mg/kgControl

Participants will wear a Bluetooth heart rate monitor chest strap throughout the test day.

(R)-1,3 butanediol 180mg/kg(R)-1,3 butanediol 360mg/kgAcAc Di-ester 180mg/kgAcAc Di-ester 360mg/kgBHB Mono-ester 180mg/kgBHB mono-ester 360mg/kgC8 Ketone Di-ester 180mg/kgC8 Ketone Di-ester 360mg/kgControl
CGM/CKMOTHER

Continuous Ketone Monitor will be applied at the start of Test Day 1. The sensor will be checked by the study team at each test day and will be removed and replaced by a fresh sensor at \~2- week intervals during the study. The sensor will be removed at the end of the final test day

(R)-1,3 butanediol 180mg/kg(R)-1,3 butanediol 360mg/kgAcAc Di-ester 180mg/kgAcAc Di-ester 360mg/kgBHB Mono-ester 180mg/kgBHB mono-ester 360mg/kgC8 Ketone Di-ester 180mg/kgC8 Ketone Di-ester 360mg/kgControl
DXARADIATION

Lean Body Mass will be assessed once via DXA

Control

Prior to consumption of the Study Product, participants will be asked to completely void bladder. And hydration status will be determined via urine specific gravity (USG) reporting \<1.025. Urine passed after the ingestion of the study product will be collected in a plastic container; participants will be asked to void their bladder and collect urine at the end of the test day. The volume produced will be recorded at the end of the study and aliquots will be frozen and stored for future analysis

(R)-1,3 butanediol 180mg/kg(R)-1,3 butanediol 360mg/kgAcAc Di-ester 180mg/kgAcAc Di-ester 360mg/kgBHB Mono-ester 180mg/kgBHB mono-ester 360mg/kgC8 Ketone Di-ester 180mg/kgC8 Ketone Di-ester 360mg/kgControl

Eligibility Criteria

Age20 Years - 30 Years
Sexmale(Gender-based eligibility)
Gender Eligibility DetailsThis study aims to recruit a homogenous, military relevant population to remove the confounding effects of variation in phenotype on exogenous ketone metabolism as far as possible. Thus, we will 15 recruit healthy and normally-active resistance/endurance trained men from the ages of 20-30 yr that represents typical active-duty military personnel.
Healthy VolunteersYes
Age GroupsAdult (18-64)

You may qualify if:

  • Male
  • BMI between 18 and 29 kg/m2
  • Aged 20 - 30 years
  • Participant is willing and able to comply with all study procedures including the following prior to Test Days: fasting (\>10 h; water only), no alcohol (\>24 h), no exercise (\>24 h), no acute illness and controlled feeding before each Test Day, maintain diet, exercise, medication, and supplement habits throughout the study.
  • Participant has no health conditions that would prevent completion of the study requirements as judged by the Investigator based on health history.
  • Participant understands the study procedures and signs forms providing informed consent to participate in the study and authorizes the release of relevant protected health information to the Investigator.

You may not qualify if:

  • Participant follows a low-carbohydrate diet (\<30% energy from carbohydrate) or have used exogenous ketone supplements within 4-months of study participation.
  • Participant has a Primary Care Physician diagnosed history or presence of uncontrolled and/or clinically important hypertension (blood pressure \>150/95 mmHg), pulmonary, cardiac, hepatic, renal, endocrine (including type 1 and 2 diabetes), hematologic, immunologic, neurologic (e.g., Alzheimer's or Parkinson's diseases), psychiatric (including unstable depression and/or anxiety disorders) or biliary disorders.
  • Participant has a known allergy, intolerance, or sensitivity to any of the ingredients in the study beverages, including soy and milk protein, wheat, shellfish, fin fish, eggs, tree nuts or peanuts (production facility handles nuts).
  • Participant has unstable use of a medication or supplement that the Investigator considers may affect the outcomes of the trial.
  • Consumption of alcohol more than 3 drinks per day or more than 18 drinks per week.
  • Consumption of tobacco.
  • Consumption of cannabis.
  • Participant is currently in another research study or has been in the 14 days before screening.
  • Participant has had a blood draw or donation in the last 8 weeks.
  • Participant has a clinically important gastrointestinal (GI) condition that would potentially interfere with the evaluation of the study beverage \[e.g., inflammatory bowel disease, irritable bowel syndrome, chronic constipation, severe constipation (in the opinion of the Investigator), history of frequent diarrhea, history of surgery for weight loss, gastroparesis, systemic disease that might affect gut motility according to the Investigator, medication managed reflux and/or clinically important lactose intolerance\].
  • Participant has a condition the Investigator believes would interfere with his ability to provide informed consent, comply with the study protocol, which might confound the interpretation of the study results, or put the participant at undue risk.

Contact the study team to confirm eligibility.

Sponsors & Collaborators

Study Sites (1)

The Ohio State University

Columbus, Ohio, 43210, United States

Location

Related Links

MeSH Terms

Conditions

Ketosis

Interventions

Blood Specimen CollectionUrinalysis

Condition Hierarchy (Ancestors)

AcidosisAcid-Base ImbalanceMetabolic DiseasesNutritional and Metabolic Diseases

Intervention Hierarchy (Ancestors)

Specimen HandlingClinical Laboratory TechniquesDiagnostic Techniques and ProceduresDiagnosisPuncturesSurgical Procedures, OperativeInvestigative TechniquesClinical Chemistry TestsDiagnostic Techniques, Urological

Study Officials

  • Jeff S Volek, PhD

    Ohio State University

    PRINCIPAL INVESTIGATOR

Study Design

Study Type
interventional
Phase
not applicable
Allocation
RANDOMIZED
Masking
NONE
Purpose
BASIC SCIENCE
Intervention Model
CROSSOVER
Sponsor Type
OTHER
Responsible Party
PRINCIPAL INVESTIGATOR
PI Title
Professor

Study Record Dates

First Submitted

August 1, 2022

First Posted

August 15, 2022

Study Start

June 5, 2023

Primary Completion (Estimated)

September 1, 2026

Study Completion (Estimated)

September 1, 2027

Last Updated

May 29, 2025

Record last verified: 2025-05

Locations